Zinc bis(trifluoromethylsulfonyl)imide, Thermo Scientific Chemicals

Product Code	Brand	Quantity
15482787	Thermo Scientific Alfa Aesar 046880.MD	250 mg
15462787	Thermo Scientific Alfa Aesar 046880.03	1 g
15472787	Thermo Scientific Alfa Aesar 046880.06	5 g

Description

Zinc bis(trifluoromethylsulfonyl)imide is used as a Catalyst for Enantioselective Friedel-Crafts alkylation of pyrroles with β-CF3 acrylates, Stereoselective Diels-Alder reaction, Tandem cyclopropane ring-opening / Conia-ene cyclization Aromatic nitration.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 168106-25-0
• Molecular Weight (g/mol): 625.651
• InChI Key: QEORIOGPVTWFMH-UHFFFAOYSA-N
• PubChem CID: 131849436
• SMILES: C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Zn+2]

• Molecular Formula: C4F12N2O8S4Zn
• MDL Number: MFCD16621474
• Synonym: Zinc triflimide; Zinc trifluoromethanesulfonimide
• IUPAC Name: zinc;bis(trifluoromethylsulfonyl)azanide

Specifications

• CAS: 168106-25-0
• Color: White
• Molecular Formula: C4F12N2O8S4Zn
• MDL Number: MFCD16621474
• Synonym: Zinc triflimide; Zinc trifluoromethanesulfonimide
• InChI Key: QEORIOGPVTWFMH-UHFFFAOYSA-N
• IUPAC Name: zinc;bis(trifluoromethylsulfonyl)azanide
• PubChem CID: 131849436
• Physical Form: Solid

• Melting Point: 143°C to 147°C
• Flash Point: >110°C (230°F)
• Linear Formula: [(CF₃SO₂)₂N]₂Zn
• Sensitivity: Moisture sensitive
• Solubility Information: It is soluble in CH2Cl2 and H2O.
• SMILES: C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Zn+2]
• Molecular Weight (g/mol): 625.651
• Formula Weight: 625.65
• Chemical Name or Material: Zinc bis (trifluoromethylsulfonyl)imide

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Argon

Product Identifier

• Zinc bis(trifluoromethylsulfonyl)imide

Signal Word

• Warning

Hazard Category

• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P302+P352-IF ON SKIN: Wash with plenty of water/soap.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P312-Call a POISON CENTER/doctor/if you feel unwell.
• P332+P313-If skin irritation occurs: Get medical advice/attention.
• P337+P313-If eye irritation persists: Get medical advice/attention.

Supplemental information

• MIXTURE LIST-Contains : Zinc bis(trifluoromethylsulfonyl)imide

RUO – Research Use Only