Vinylmagnesium bromide, 0.7M solution in THF, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10759344	Thermo Scientific Acros 209391000	100 mL	AcroSeal™ Glass bottle
10198262	Thermo Scientific Acros 209398000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 1826-67-1, 109-99-9
• Molecular Weight (g/mol): 131.26
• InChI Key: XHHHAXOHMKAOSL-UHFFFAOYSA-M
• PubChem CID: 74584

• Molecular Formula: C2H3BrMg
• MDL Number: MFCD00000042
• Synonym: vinylmagnesium bromide, bromo ethenyl magnesium, vinyl magnesium bromide, magnesium, bromoethenyl, vinylmagnesium bromide solution, vinylmagnesium bromide solution, 1.0 m in thf, bromovinylmagnesium, bromo vinyl magnesium, vinyl magnesiumbromide, grignard reagent
• SMILES: Br[Mg]C=C

Specifications

• Color: Brown
• Molecular Formula: C2H3BrMg
• MDL Number: MFCD00000042
• Density: 0.9800g/mL
• Solubility Information: Solubility in water: vigorous reaction.
• SMILES: Br[Mg]C=C
• Molecular Weight (g/mol): 131.26
• Formula Weight: 131.25
• Flash Point: −17°C
• Chemical Name or Material: Vinylmagnesium bromide, 0.7M Solution in THF

• CAS: 1826-67-1, 109-99-9
• Linear Formula: H₂C=CHMgBr
• Concentration: 0.7 to 0.9M
• Synonym: vinylmagnesium bromide, bromo ethenyl magnesium, vinyl magnesium bromide, magnesium, bromoethenyl, vinylmagnesium bromide solution, vinylmagnesium bromide solution, 1.0 m in thf, bromovinylmagnesium, bromo vinyl magnesium, vinyl magnesiumbromide, grignard reagent
• InChI Key: XHHHAXOHMKAOSL-UHFFFAOYSA-M
• IUPAC Name: bromo(ethenyl)magnesium
• PubChem CID: 74584
• Specific Gravity: 0.98
• Physical Form: Solution

Safety and Handling

GHS P Statement

Causes severe skin burns and eye damage.
In contact with water releases flammable gases which may ignite spontaneously.
May cause respiratory irritation.
Highly flammable liquid and vapor.
Reacts violently with water.

GHS P Statement
Store in a dry place. Store in a closed container.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Danger

Product Identifier

• Vinylmagnesium bromide, 0.7M solution in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only