Vanadium(V) trichloride oxide, V+5 28.5% min, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11354919	Thermo Scientific Alfa Aesar 081118.09	10 g
11344919	Thermo Scientific Alfa Aesar 081118.22	100 g
11364919	Thermo Scientific Alfa Aesar 081118.36	500 g

Description

Vanadium(V) trichloride oxide is used as a catalyst in olefin polymerization reaction, especially for the production of ethylene-propylene rubber. It is also used to synthesis organovanadium compounds and as a mordant in dyeing. It acts as a precursor to prepare vanadium pentoxide, vanadyl dichloride and dioxovanadium monochloride. Further, it serves as a reagent and a strong oxidizing agent in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 7727-18-6
• Molecular Weight (g/mol): 173.29
• InChI Key: WMZFXRASJAIALG-UHFFFAOYSA-K
• PubChem CID: 24410
• SMILES: [Cl-].[Cl-].[Cl-].O=[V+5]

• Molecular Formula: Cl3OV
• MDL Number: MFCD00011459
• Synonym: vanadyl trichloride, trichlorooxovanadium, vanadium v trichloride oxide, trichlorooxovanadium oxide, vanadium v oxytrichloride, trichlorooxo vanadium, vanadium, trichlorooxo-, t-4, vanadium, trichlorooxo, vanadium oxide trichloride, vanadium trichloride oxide
• IUPAC Name: oxovanadium;trihydrochloride

Specifications

• Boiling Point: 126°C to 127°C
• CAS: 7727-18-6
• Physical Form: Liquid
• MDL Number: MFCD00011459
• Merck Index: 14,9927
• Solubility Information: Miscible with benzene,dichloromethane and hexane.
• SMILES: [Cl-].[Cl-].[Cl-].O=[V+5]
• Molecular Weight (g/mol): 173.29
• Formula Weight: 173.3
• Odor: Chlorine-like
• Density: 1.829 g/mL

• Melting Point: -77°C
• Color: Yellow
• Molecular Formula: Cl3OV
• UN Number: UN2443
• Synonym: vanadyl trichloride, trichlorooxovanadium, vanadium v trichloride oxide, trichlorooxovanadium oxide, vanadium v oxytrichloride, trichlorooxo vanadium, vanadium, trichlorooxo-, t-4, vanadium, trichlorooxo, vanadium oxide trichloride, vanadium trichloride oxide
• InChI Key: WMZFXRASJAIALG-UHFFFAOYSA-K
• IUPAC Name: oxovanadium;trihydrochloride
• PubChem CID: 24410
• Concentration or Composition (by Analyte or Components): V+5 28.5% min
• Sensitivity: Moisture sensitive
• Chemical Name or Material: Vanadium (V) trichloride oxide

Safety and Handling

GHS H Statement
H301-H314-H318
Toxic if swallowed.
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: VANADIUM OXYTRICHLORIDE

missing translation for 'einecsNumber' : 231-780-2

missing translation for 'rtecsNumber' : YW2975000

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

Product Identifier

• Vanadium(V) trichloride oxide

Signal Word

• Danger

Hazard Category

• LONG-TERM AQUATIC HAZARD Chronic 3
• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B

Hazard Statement

• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H412-Harmful to aquatic life with long lasting effects.
• EUH014-Reacts violently with water.
• EUH029-Contact with water liberates toxic gas.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Vanadium oxytrichloride

RUO – Research Use Only