Titanium(IV) chloride, 1M soln. in dichloromethane, Thermo Scientific Chemicals

Product Code	Brand	Quantity
15417915	Thermo Scientific Alfa Aesar H31830.AE	100 mL
15427915	Thermo Scientific Alfa Aesar H31830.AP	500 mL

Description

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

Solubility
Reacts with water.

Notes
Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers

Chemical Identifiers

• CAS: 7550-45-0
• Molecular Weight (g/mol): 189.667
• InChI Key: XJDNKRIXUMDJCW-UHFFFAOYSA-J
• PubChem CID: 160960
• SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[Ti+4]

• Molecular Formula: Cl4Ti
• MDL Number: MFCD00011267
• Synonym: titanium iv chloride, titanium 4+ tetrachloride, acmc-1bjgv, titanium 4+ ion tetrachloride, parent, titanium +4 cation tetrachloride, titanium iv chloride 100ml, superlist names titanium chloride, t-4, titanic chloride; titanio tetracloruro di, unii-8o3pje5t7q; titanium chloride ticl4
• IUPAC Name: titanium(4+);tetrachloride

Specifications

• CAS: 7550-45-0
• Linear Formula: TiCl₄
• UN Number: UN2922
• Solubility Information: Reacts with water.
• SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[Ti+4]
• Molecular Weight (g/mol): 189.667
• Formula Weight: 189.69
• Sensitivity: Moisture sensitive; May form a precipitate
• Chemical Name or Material: Titanium(IV) chloride

• Molecular Formula: Cl4Ti
• MDL Number: MFCD00011267
• Synonym: titanium iv chloride, titanium 4+ tetrachloride, acmc-1bjgv, titanium 4+ ion tetrachloride, parent, titanium +4 cation tetrachloride, titanium iv chloride 100ml, superlist names titanium chloride, t-4, titanic chloride; titanio tetracloruro di, unii-8o3pje5t7q; titanium chloride ticl4
• InChI Key: XJDNKRIXUMDJCW-UHFFFAOYSA-J
• IUPAC Name: titanium(4+);tetrachloride
• PubChem CID: 160960
• Concentration or Composition (by Analyte or Components): 1M soln. in dichloromethane
• Density: 1.365

Safety and Handling

GHS H Statement
H314-H351
Causes severe skin burns and eye damage.
Suspected of causing cancer.

P201-P202-P260-P264b-P271-P281-P284-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H331-H335-H336-H351

missing translation for 'dotInformation' : Hazard Class: 8; Packaging Group: II

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

Product Identifier

• Titanium(IV) chloride, 1M solution in dichloromethane

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 3
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3

Hazard Statement

• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H331-Toxic if inhaled.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H351-Suspected of causing cancer.
• EUH014-Reacts violently with water.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Dichloromethane, Titanium tetrachloride

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RUO – Research Use Only