sec-Butyllithium, 1.3M sol. in cyclohexane/hexane (92/8), AcroSeal™, Thermo Scientific Chemicals

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 598-30-1, 110-82-7, 110-54-3
• Molecular Formula: C4H9Li
• Molecular Weight (g/mol): 64.06
• MDL Number: MFCD00009323
• InChI Key: VATDYQWILMGLEW-UHFFFAOYNA-N
• Synonym: sec-butyllithium, s-buli, s-butyllithium, s-butyl lithium, unii-5yv3gii1tb, lithium, 1-methylpropyl, 5yv3gii1tb, secbutyllithium, b-butyllithium, sec-butyllitium
• PubChem CID: 102446
• IUPAC Name: (butan-2-yl)lithium
• SMILES: [Li]C(C)CC

• Color: Colorless
• Linear Formula: C₂H₅CH(CH₃)Li
• Fieser: 09,87; 10,75; 12,97; 16,56
• Density: 0.7500g/mL
• Solubility Information: Solubility in water: reacts (forming lioh and butane).
• Formula Weight: 64.06
• Percent Purity: 10.5 to 12.5% (as BuLi) (Active base)
• Packaging: AcroSeal™ Glass Bottle
• Specific Gravity: 0.75
• Quantity: 800 mL
• Flash Point: −17°C
• Physical Form: Liquid
• Chemical Name or Material: sec-Butyllithium, 1.3M Solution in Cyclohexane/hexane (92/8)

Safety and Handling

Signal Word

• Danger

Hazard Category

• ACUTE AQUATIC Acute 1
• LONG-TERM AQUATIC HAZARD Chronic 1
• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Pyrophoric liquid Category 1
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H304-May be fatal if swallowed and enters airways.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H336-May cause drowsiness or dizziness.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• H400-Very toxic to aquatic life.
• H410-Very toxic to aquatic life with long lasting effects.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P222-Do not allow contact with air.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only