Ruthenium(III) 2,4-pentanedionate, Ru 24% min, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11300729	Thermo Scientific Alfa Aesar 010568.03	1 g
11310729	Thermo Scientific Alfa Aesar 010568.06	5 g

Description

Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 14284-93-6
• Molecular Weight (g/mol): 398.40
• InChI Key: RTZYCRSRNSTRGC-LNTINUHCSA-K
• PubChem CID: 5488829

• Molecular Formula: C15H21O6Ru
• MDL Number: MFCD00000030
• Synonym: ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+
• SMILES: [Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O

Specifications

• Melting Point: 260°C (decomposition)
• Color: White
• Molecular Formula: C15H21O6Ru
• Synonym: ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+
• InChI Key: RTZYCRSRNSTRGC-LNTINUHCSA-K
• IUPAC Name: (Z)-4-oxopent-2-en-2-olate;ruthenium(3+)
• PubChem CID: 5488829
• Appearance: Red crystals

• CAS: 14284-93-6
• Physical Form: Crystalline
• MDL Number: MFCD00000030
• Solubility Information: Soluble in most organic solvents such as acetone,chlorinated hydrocarbons,alcohols,cyclohexane and benzene. Insoluble in water.
• SMILES: [Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
• Molecular Weight (g/mol): 398.40
• Formula Weight: 398.4
• Chemical Name or Material: Ruthenium(III) 2, 4-pentanedionate, Ru 24% min.

Safety and Handling

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

missing translation for 'einecsNumber' : 238-193-0

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

RUO – Research Use Only