Rhodium(II) acetate, dimer, Premion™, 99.99% (metals basis), Rh 46.2% min, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11380709	Thermo Scientific Alfa Aesar 010560.01	0.25 g
11370709	Thermo Scientific Alfa Aesar 010560.03	1 g

Description

Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving -diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 15956-28-2
• Molecular Weight (g/mol): 441.99
• InChI Key: VOXKIADTKKPBBP-UHFFFAOYSA-N
• PubChem CID: 122130469

• Molecular Formula: C8H12O8Rh2
• MDL Number: MFCD00003538
• Synonym: rhodium ii acetate, rhodium diacetate, acetic acid, rhodium 2+ salt, rhodium ii acetate dimer dihydrate, dirhodium tetraacetate, rhodium ii acetate dimer, rhodium acetate, brown, water soluble, diacetoxyrhodium
• SMILES: C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4

Specifications

• Melting Point: 205°C
• Color: Green
• Assay Percent Range: 99.99% (metals basis)
• MDL Number: MFCD00003538
• Solubility Information: Soluble in aqueous solution like water. Slightly soluble in ethanol
• SMILES: C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4
• Molecular Weight (g/mol): 441.99
• Formula Weight: 441.99
• Appearance: Green powder

• CAS: 15956-28-2
• Physical Form: Powder
• Molecular Formula: C8H12O8Rh2
• Synonym: rhodium ii acetate, rhodium diacetate, acetic acid, rhodium 2+ salt, rhodium ii acetate dimer dihydrate, dirhodium tetraacetate, rhodium ii acetate dimer, rhodium acetate, brown, water soluble, diacetoxyrhodium
• InChI Key: VOXKIADTKKPBBP-UHFFFAOYSA-N
• IUPAC Name: rhodium(2+);tetraacetate
• PubChem CID: 122130469
• Odor: Odorless
• Chemical Name or Material: Rhodium(II) acetate, dimer, Rh 46.2% min.

Safety and Handling

P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362

H315-H319

missing translation for 'einecsNumber' : 240-084-8

missing translation for 'rtecsNumber' : VI9361000

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

Product Identifier

• Rhodium(II) acetate, dimer

Signal Word

• Warning

Hazard Category

• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2

Hazard Statement

• H315-Causes skin irritation.
• H319-Causes serious eye irritation.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P302+P352-IF ON SKIN: Wash with plenty of water/soap.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental information

• MIXTURE LIST-Contains : Rhodium(II) acetate

RUO – Research Use Only