Rhodium(II) acetate, dimer, 98+%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11358176	Thermo Scientific Alfa Aesar L15152.MC	100 mg
11338176	Thermo Scientific Alfa Aesar L15152.ME	500 mg
11348176	Thermo Scientific Alfa Aesar L15152.04	2 g

Description

Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ?-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving ɑ-diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.

Solubility
Soluble in aqueous solution like water. Slightly soluble in ethanol

Notes
Stable under normal conditions.

Chemical Identifiers

• CAS: 15956-28-2
• Molecular Weight (g/mol): 441.99
• InChI Key: VOXKIADTKKPBBP-UHFFFAOYSA-N
• PubChem CID: 122130469

• Molecular Formula: C8H12O8Rh2
• MDL Number: MFCD00003538
• Synonym: rhodium ii acetate, rhodium diacetate, acetic acid, rhodium 2+ salt, rhodium ii acetate dimer dihydrate, dirhodium tetraacetate, rhodium ii acetate dimer, rhodium acetate, brown, water soluble, diacetoxyrhodium
• SMILES: C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4

Specifications

• Melting Point: 205°C
• Molecular Formula: C8H12O8Rh2
• MDL Number: MFCD00003538
• Solubility Information: Soluble in aqueous solution like water. Slightly soluble in ethanol
• SMILES: C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4
• Molecular Weight (g/mol): 441.99
• Formula Weight: 441.99
• Odor: Odorless

• CAS: 15956-28-2
• Linear Formula: [Rh(CO₂CH₃)₂]₂
• Synonym: rhodium ii acetate, rhodium diacetate, acetic acid, rhodium 2+ salt, rhodium ii acetate dimer dihydrate, dirhodium tetraacetate, rhodium ii acetate dimer, rhodium acetate, brown, water soluble, diacetoxyrhodium
• InChI Key: VOXKIADTKKPBBP-UHFFFAOYSA-N
• IUPAC Name: bis(λ²-rhodium(2+)) tetraacetate
• PubChem CID: 122130469
• Percent Purity: ≥98%
• Chemical Name or Material: Rhodium(II) acetate, dimer

Safety and Handling

P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362

H315-H319

missing translation for 'einecsNumber' : 240-084-8

missing translation for 'rtecsNumber' : VI9361000

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

RUO – Research Use Only