Propargyl bromide, 80 wt.% solution in toluene, stabilized, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10285370	Thermo Scientific Acros 131480500	50 mL	Glass bottle
10665182	Thermo Scientific Acros 131482500	250 mL	Glass bottle
11944491	Thermo Scientific Acros 131480010	1 L	AcroSeal™ Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Alkylation reagent

Specifications

• Chemical Name or Material: Propargyl bromide
• CAS: 106-96-7, 108-88-3
• Molecular Formula: C3H3Br
• Fieser: 06,493; 10,332; 06,495
• Synonym: propargyl bromide, 3-bromopropyne, 3-bromo-1-propyne, 1-propyne, 3-bromo, 2-propynyl bromide, propynyl bromide, 1-bromo-2-propyne, propyne, 3-bromo, gamma-bromoallylene, 1-brom-2-propin
• InChI Key: YORCIIVHUBAYBQ-UHFFFAOYSA-N
• IUPAC Name: 3-bromoprop-1-yne
• PubChem CID: 7842
• Percent Purity: 73 to 87% (propargyl bromide) (GC) 13 to 27% (toluene) (GC)
• Specific Gravity: 1.38
• Physical Form: Powder

• Color: White
• Boiling Point: 88.0°C to 90.0°C
• Linear Formula: HC≡CCH₂Br
• Density: 1.3800g/mL
• Solubility Information: Solubility in water: immiscible.
• SMILES: C#CCBr
• Molecular Weight (g/mol): 118.961
• Formula Weight: 118.96
• Refractive Index: 1.4900 to 1.4960
• Flash Point: 4°C

Safety and Handling

Danger

Product Identifier

• Propargyl bromide, 80 wt% solution in toluene, stabilized

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 3
• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H361-Suspected of damaging fertility or the unborn child.
• H373-May cause damage to organs.
• H331-Toxic if inhaled.
• H336-May cause drowsiness or dizziness.
• H225-Highly flammable liquid and vapour.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P240-Ground/bond container and receiving equipment.
• P260-Do not breathe dust/fume/gas/mist/vapours/spray.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P331-Do NOT induce vomiting.

RUO – Research Use Only