Nitronium tetrafluoroborate, 96%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11479586	Thermo Scientific Alfa Aesar B20167.06	5 g
11489586	Thermo Scientific Alfa Aesar B20167.14	25 g
11499586	Thermo Scientific Alfa Aesar B20167.22	100 g

Description

Nitronium tetrafluoroborate has been shown to be a versatile nitrating agent for nitrogen compounds, giving the corresponding N-nitro derivative when reacted with secondary aliphatic amines, an acyl aliphatic amine, a carbamate ester: a diacyl amine and primary amides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Nitronium tetrafluoroborate has been shown to be a versatile nitrating agent for nitrogen compounds, giving the corresponding N-nitro derivative when reacted with secondary aliphatic amines, an acyl aliphatic amine, a carbamate ester: a diacyl amine and primary amides.

Solubility
Decomposes in water.

Notes
Moisture sensitive. Store away from oxidizing agents, bases, water/moisture and heat. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. Keep it refrigerated.

Chemical Identifiers

• CAS: 13826-86-3
• Molecular Weight (g/mol): 132.81
• InChI Key: XYRQURYIJKJVSF-UHFFFAOYSA-N
• PubChem CID: 11073463

• Molecular Formula: BF4NO2
• MDL Number: MFCD00011432
• Synonym: nitronium tetrafluoroborate, nitronium ion tetrafluoroborate, nitronium tetrafluoroboron, nitroniumtetrafluoroborate, nitronium.tetrafluoroborate, nitronium tetrafluoroborate, 0.3-0.5m solution in sulfolane
• SMILES: [O-][NH+]=O.F[B-](F)(F)F

Specifications

• Melting Point: ∽240°C (decomposition)
• Molecular Formula: BF4NO2
• MDL Number: MFCD00011432
• Synonym: nitronium tetrafluoroborate, nitronium ion tetrafluoroborate, nitronium tetrafluoroboron, nitroniumtetrafluoroborate, nitronium.tetrafluoroborate, nitronium tetrafluoroborate, 0.3-0.5m solution in sulfolane
• InChI Key: XYRQURYIJKJVSF-UHFFFAOYSA-N
• IUPAC Name: nitronium;tetrafluoroborate
• PubChem CID: 11073463
• Percent Purity: 96%
• Chemical Name or Material: Nitronium tetrafluoroborate

• CAS: 13826-86-3
• Linear Formula: NO₂BF₄
• UN Number: UN3260
• Solubility Information: Decomposes in water.
• SMILES: [O-][NH+]=O.F[B-](F)(F)F
• Molecular Weight (g/mol): 132.81
• Formula Weight: 132.81
• Sensitivity: Moisture sensitive

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P280-P285-P301+P330+P331-P303+P361+P353-P304+P341-P305+P351+P338-P310-P342+P311-P363-P501c

H314-H334

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missing translation for 'tsca' : Yes

Recommended Storage : Keep cold; Store under Nitrogen

RUO – Research Use Only