Nitronium tetrafluoroborate, 90%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11347818	Thermo Scientific Alfa Aesar 036374.06	5 g
11337818	Thermo Scientific Alfa Aesar 036374.14	25 g

Description

Ingold's method of competitive nitration has been used in order to determine relative reactivities of alkylbenzenes and benzene in homogeneous mononitrations with nitronium tetrafluoroborate in tetramethylene sulfone solutions. Oxidation of both exo-and endo-2-bromonorbornane with nitronium tetrafluoroborate in acetonitrile afforded N-exo-2-norbornylacetamide. Used in the synthesis and characterization of new polyhydroxyorganocarboxylated fullerene derivatives through the electrophilic addition of nitronium tetrafluoroborate onto fullerenes in the presence of arenecarboxylic acid in a nonaqueous medium.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 13826-86-3
• Molecular Weight (g/mol): 132.81
• InChI Key: XYRQURYIJKJVSF-UHFFFAOYSA-N
• PubChem CID: 11073463
• SMILES: [O-][NH+]=O.F[B-](F)(F)F

• Molecular Formula: BF4NO2
• MDL Number: MFCD00011432
• Synonym: nitronium tetrafluoroborate, nitronium ion tetrafluoroborate, nitronium tetrafluoroboron, nitroniumtetrafluoroborate, nitronium.tetrafluoroborate, nitronium tetrafluoroborate, 0.3-0.5m solution in sulfolane
• IUPAC Name: nitronium;tetrafluoroborate

Specifications

• Melting Point: 240°C (dec.)
• Color: White
• Molecular Formula: BF4NO2
• MDL Number: MFCD00011432
• Synonym: nitronium tetrafluoroborate, nitronium ion tetrafluoroborate, nitronium tetrafluoroboron, nitroniumtetrafluoroborate, nitronium.tetrafluoroborate, nitronium tetrafluoroborate, 0.3-0.5m solution in sulfolane
• InChI Key: XYRQURYIJKJVSF-UHFFFAOYSA-N
• IUPAC Name: nitronium;tetrafluoroborate
• PubChem CID: 11073463
• Percent Purity: 90%
• Chemical Name or Material: Nitronium tetrafluoroborate

• CAS: 13826-86-3
• Physical Form: Crystalline
• Linear Formula: NO₂BF₄
• UN Number: UN3260
• Solubility Information: Decomposes in water.
• SMILES: [O-][NH+]=O.F[B-](F)(F)F
• Molecular Weight (g/mol): 132.81
• Formula Weight: 132.81
• Sensitivity: Moisture sensitive

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P280-P285-P301+P330+P331-P303+P361+P353-P304+P341-P305+P351+P338-P310-P342+P311-P363-P501c

H314-H334

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.

missing translation for 'einecsNumber' : 237-533-5

missing translation for 'rtecsNumber' : QX8620000

missing translation for 'tsca' : Yes

missing translation for 'storageNote' : 2°C to 8°C

Recommended Storage : Keep cold; Store under Nitrogen

RUO – Research Use Only