Ethylmagnesium bromide, 0.9M solution in THF, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10570633	Thermo Scientific Acros 210471000	100 mL	AcroSeal™ Glass bottle
10444833	Thermo Scientific Acros 210478000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 925-90-6, 109-99-9
• Molecular Weight (g/mol): 133.27
• InChI Key: TWTWFMUQSOFTRN-UHFFFAOYSA-M
• PubChem CID: 101914

• Molecular Formula: C2H5BrMg
• MDL Number: MFCD00000043
• Synonym: ethylmagnesium bromide, ethyl magnesium bromide, magnesium, bromoethyl, ethylmagnesiumbromide, bromoethylmagnesium, ethylmagnesium bromide solution, 1.0 m in thf, ethylmagnesium bromide solution, 3.0 m in diethyl ether, etmgbr, ethylmagnesiumbromid, ethylmagnesium bromid, grignard reagent
• SMILES: CC[Mg]Br

Specifications

• Color: Black-Brown to Brown
• Molecular Formula: C2H5BrMg
• MDL Number: MFCD00000043
• Fieser: 02,205; 08,510; 11,574
• Synonym: ethylmagnesium bromide, ethyl magnesium bromide, magnesium, bromoethyl, ethylmagnesiumbromide, bromoethylmagnesium, ethylmagnesium bromide solution, 1.0 m in thf, ethylmagnesium bromide solution, 3.0 m in diethyl ether, etmgbr, ethylmagnesiumbromid, ethylmagnesium bromid, grignard reagent
• InChI Key: TWTWFMUQSOFTRN-UHFFFAOYSA-M
• IUPAC Name: magnesium;ethane;bromide
• PubChem CID: 101914
• Specific Gravity: 1.01
• Physical Form: Solution

• CAS: 925-90-6, 109-99-9
• Linear Formula: C₂H₅MgBr
• Concentration: 0.85 to 1.15M
• Density: 1.0100g/mL
• Solubility Information: Solubility in water: vigorous reaction.
• SMILES: CC[Mg]Br
• Molecular Weight (g/mol): 133.27
• Formula Weight: 133.27
• Flash Point: −17°C
• Chemical Name or Material: Ethylmagnesium bromide, 1M Solution in THF

Safety and Handling

GHS H Statement
Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. Harmful if swallowed. May cause respiratory irritation. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Suspected of causing cancer. Reacts violently with water. May form explosive peroxides.

GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Danger

Product Identifier

• Ethyl magnesiumbromide, 1M solution in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only