Dimethylzinc, 1.2M solution in toluene, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10403073	Thermo Scientific Acros 377241000	100 mL	AcroSeal™ Glass bottle
10689414	Thermo Scientific Acros 377248000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

• Chemical Name or Material: Dimethylzinc
• Name Note: 1.2M Solution in Toluene
• Molecular Formula: C2H6Zn
• MDL Number: MFCD00014854
• Density: 0.9300g/mL
• Synonym: dimethylzinc, zinc, dimethyl, dimethyl zinc, methylzinc, unii-8h6r0n8w2f, ch3 2zn, znme2, zinc methyl, dimethylzink, hsdb 709
• InChI Key: JRPGMCRJPQJYPE-UHFFFAOYSA-N
• IUPAC Name: zinc;carbanide
• PubChem CID: 11010
• Specific Gravity: 0.93

• Color: Clear colorless
• CAS: 544-97-8, 108-88-3
• Linear Formula: Zn(CH₃)₂
• Concentration: 1.2M (based on Zn) exact strength on the certificate of analysis
• Merck Index: 15, 3289
• Solubility Information: Solubility in water: vigorous reaction. Other solubilities: soluble in hydrocarbons
• SMILES: [CH3-].[CH3-].[Zn+2]
• Molecular Weight (g/mol): 95.45
• Formula Weight: 95.45

Safety and Handling

GHS H Statement
Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. Reacts violently with water.

GHS P Statement
Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Store in a dry place. Store in a closed container.

Danger

Product Identifier

• Dimethylzinc, 1.2M solution in toluene

Signal Word

• Danger

Hazard Category

• Flammable liquid Category 2
• Aspiration toxicity Category 1
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3
• Reproductive toxicity Category 2
• Specific target organ toxicity after repeated exposure Category 2
• Pyrophoric liquid Category 1
• Substance which\, in contact with water\, emits flammable gases Category 1
• Skin corrosion/irritation Category 1 B
• Serious eye damage/eye irritation Category 1
• LONG-TERM AQUATIC HAZARD Chronic 1

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H304-May be fatal if swallowed and enters airways.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• H361d-Suspected of damaging the unborn child.
• H373-May cause damage to organs.
• H411-Toxic to aquatic life with long lasting effects.
• EUH014-Reacts violently with water.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P310-Immediately call a POISON CENTER/doctor/.
• P402+P404-Store in a dry place. Store in a closed container.

Supplemental information

• MIXTURE LIST-Contains : Toluene, Dimethyl zinc

RUO – Research Use Only