Diisobutylaluminium hydride, 1.2M (20 wt%) solution in toluene, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10143011	Thermo Scientific Acros 201081000	100 mL	AcroSeal™ Glass bottle
10521841	Thermo Scientific Acros 201084000	400 mL	AcroSeal™ Glass Bottle
10667114	Thermo Scientific Acros 201088000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Lewis acid, Reduction reagent

Specifications

• Chemical Name or Material: Diisobutylaluminium hydride
• Density: 0.8480g/mL
• Flash Point: 4°C
• Linear Formula: [(CH₃)₂CHCH₂]₂AIH
• Beilstein: 04, IV, 4400
• Merck Index: 15, 3212
• Synonym: DIBAL-H
• Molecular Weight (g/mol): 142.22
• Physical Form: Solution

• CAS: 1191-15-7, 108-88-3
• Boiling Point: 110.0°C
• Molecular Formula: C₈H₁₉Al
• MDL Number: MFCD00008928
• Fieser: 01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
• Specific Gravity: 0.848
• Solubility Information: Solubility in water: reacts violently. Other solubilities: miscible with saturated aliphatic and aromatic,hydrocarbons
• Formula Weight: 142.22

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage.
May be fatal if swallowed and enters airways.
May cause damage to organs through prolonged or repeated exposure.
Suspected of damaging the unborn child.
May cause dro

GHS P Statement
IF SWALLOWED: rinse mouth.
Do NOT induce vomiting.
Wear eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if present and easy to do.
Continue rinsi

GHS Signal Word: Danger

missing translation for 'einecsNumber' : 214-729-9

Product Identifier

• Diisobutylaluminium hydride, 20 wt% solution in toluene

Signal Word

• Danger

Hazard Category

• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 A
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H361d-Suspected of damaging the unborn child.
• H373-May cause damage to organs.
• H336-May cause drowsiness or dizziness.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P240-Ground/bond container and receiving equipment.
• P243-Take precautionary measures against static discharge.
• P260-Do not breathe dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P331-Do NOT induce vomiting.
• P402+P404-Store in a dry place. Store in a closed container.
• P403+P235-Store in a well-ventilated place. Keep cool.

RUO – Research Use Only