Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
15436655	Thermo Scientific Alfa Aesar 044971.03	1 g
15446655	Thermo Scientific Alfa Aesar 044971.06	5 g

Description

Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 29964-62-3
• Molecular Weight (g/mol): 603.80
• InChI Key: JQXJBXVWVPVTOO-UHFFFAOYSA-L
• PubChem CID: 10974057
• SMILES: Cl[Pd]Cl.C(CCP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1

• Molecular Formula: C28H28Cl2P2Pd
• MDL Number: MFCD02093437
• Synonym: 1,4-bis diphenylphosphino butane-palladium ii chloride, 1,4-butylenebis diphenylphosphine palladium dichloride, pdcl2 dppb, 1,4-bis diphenylphosphino butane palladium ii dichloride, palladium ii chloride-1,4-bis diphenylphosphine butane, dichloro bis 1,4-diphenylphosphino butane palladium ii, palladium ii chloride 1,4-bis diphenylphosphino butane complex, dichloro 1,4-bis diphenylphosphino butane palladium ii, pd dppb cl2, acmc-209sk1
• IUPAC Name: dichloropalladium;4-diphenylphosphanylbutyl(diphenyl)phosphane

Specifications

• CAS: 29964-62-3
• MDL Number: MFCD02093437
• Solubility Information: Soluble in ethanol,benzene,and ethereal solvents.
• SMILES: Cl[Pd]Cl.C(CCP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1
• Molecular Weight (g/mol): 603.80
• Formula Weight: 603.8
• Physical Form: Lumps

• Molecular Formula: C28H28Cl2P2Pd
• Synonym: 1,4-bis diphenylphosphino butane-palladium ii chloride, 1,4-butylenebis diphenylphosphine palladium dichloride, pdcl2 dppb, 1,4-bis diphenylphosphino butane palladium ii dichloride, palladium ii chloride-1,4-bis diphenylphosphine butane, dichloro bis 1,4-diphenylphosphino butane palladium ii, palladium ii chloride 1,4-bis diphenylphosphino butane complex, dichloro 1,4-bis diphenylphosphino butane palladium ii, pd dppb cl2, acmc-209sk1
• InChI Key: JQXJBXVWVPVTOO-UHFFFAOYSA-L
• IUPAC Name: dichloropalladium;4-diphenylphosphanylbutyl(diphenyl)phosphane
• PubChem CID: 10974057
• Concentration or Composition (by Analyte or Components): Pd 17.6%
• Chemical Name or Material: Dichloro[bis (1,4-diphenylphosphino)butane]palladium (II)

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures

Product Identifier

• Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II)

Signal Word

• Warning

Hazard Category

• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P302+P352-IF ON SKIN: Wash with plenty of water/soap.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P312-Call a POISON CENTER/doctor/if you feel unwell.
• P332+P313-If skin irritation occurs: Get medical advice/attention.
• P337+P313-If eye irritation persists: Get medical advice/attention.

Supplemental information

• MIXTURE LIST-Contains : Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II)

RUO – Research Use Only