Boron trichloride, 1M soln. in hexanes, mixed isomers, Thermo Scientific Chemicals

Product Code	Brand	Quantity
15418215	Thermo Scientific Alfa Aesar H32833.AE	100 mL
15428215	Thermo Scientific Alfa Aesar H32833.AP	500 mL

Description

A mild, selective combination reagent for the cleavage of primary alkyl aryl ethers. Boron trichloride is a selective demethylating agent. For preparing methyl esters of fatty acids and for transesterification of triglycerides. Mainly used as semiconductor silicon doping source or organic synthesis catalyst, also used for making high purity boron or organic boron.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
A mild, selective combination reagent for the cleavage of primary alkyl aryl ethers. Boron trichloride is a selective demethylating agent. For preparing methyl esters of fatty acids and for transesterification of triglycerides. Mainly used as semiconductor silicon doping source or organic synthesis catalyst, also used for making high purity boron or organic boron.

Solubility
Reacts with water.

Notes
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, heat. Unstable. Store at 2-8°C.

Chemical Identifiers

• CAS: 10294-34-5
• Molecular Weight (g/mol): 117.16
• InChI Key: FAQYAMRNWDIXMY-UHFFFAOYSA-N
• PubChem CID: 25135
• SMILES: ClB(Cl)Cl

• Molecular Formula: BCl3
• MDL Number: MFCD00011313
• Synonym: boron trichloride, borane, trichloro, boron chloride, trichloroboron, borontrichloride, chlorure de bore french, unii-k748471rag, hsdb 326, boron trichloride un1741 poison gas
• IUPAC Name: trichloroborane

Specifications

• CAS: 10294-34-5
• Linear Formula: BCl₃
• UN Number: UN3286
• Solubility Information: Reacts with water.
• SMILES: ClB(Cl)Cl
• Molecular Weight (g/mol): 117.16
• Formula Weight: 117.17
• Sensitivity: Moisture sensitive; May form a precipitate
• Chemical Name or Material: Boron trichloride, mixed isomers

• Molecular Formula: BCl3
• MDL Number: MFCD00011313
• Synonym: boron trichloride, borane, trichloro, boron chloride, trichloroboron, borontrichloride, chlorure de bore french, unii-k748471rag, hsdb 326, boron trichloride un1741 poison gas
• InChI Key: FAQYAMRNWDIXMY-UHFFFAOYSA-N
• IUPAC Name: trichloroborane
• PubChem CID: 25135
• Concentration or Composition (by Analyte or Components): 1M soln. in hexanes
• Density: 0.738

Safety and Handling

GHS H Statement
H225-H300-H331-H304-H361-H373-H314-H336
Highly flammable liquid and vapor.
Fatal if swallowed.
Toxic if inhaled.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.

P201-P202-P210-P233-P240-P241-P242-P243-P261-P262-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P331-P363-P372-P374-P380-P501c

H225-H300+H330-H314-H318-H361-H373-X

missing translation for 'dotInformation' : Hazard Class: 3; Packaging Group: I

missing translation for 'einecsNumber' : 233-658-4

missing translation for 'tsca' : Yes

Recommended Storage : Keep cold; Store under Nitrogen

Product Identifier

• Boron trichloride, 1M solution in hexanes, mixed isomers

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 2
• LONG-TERM AQUATIC HAZARD Chronic 2
• Aspiration toxicity Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H300-Fatal if swallowed.
• H304-May be fatal if swallowed and enters airways.
• H314-Causes severe skin burns and eye damage.
• H330-Fatal if inhaled.
• H336-May cause drowsiness or dizziness.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• H411-Toxic to aquatic life with long lasting effects.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P402+P404-Store in a dry place. Store in a closed container.

Supplemental information

• MIXTURE LIST-Contains : Hexane, Boron trichloride

RUO – Research Use Only