Boron tribromide, 1M solution in methylene chloride, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10398190	Thermo Scientific Acros 198900100	10 mL	Glass bottle
10552221	Thermo Scientific Acros 198901000	100 mL	Glass bottle
10733894	Thermo Scientific 198908000	800 mL	Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

C-X bond formation reagent, Lewis acid

Specifications

• Chemical Name or Material: Boron tribromide
• CAS: 10294-33-4, 75-09-2
• Physical Form: Solution
• Linear Formula: BBr₃
• Fieser: 01,66; 02,33; 03,30; 04,42; 05,49; 06,64; 09,61; 10,50; 11,71; 13,43
• Synonym: boron tribromide, borane, tribromo, boron bromide, tribromoboron, hsdb 327, tribromoboran, boron tribrornide, boron tri bromide, boron tri-bromide
• SMILES: BrB(Br)Br
• Molecular Weight (g/mol): 250.52
• Formula Weight: 250.52
• Packaging: Glass bottle
• Density: 1.4670g/mL

• Name Note: 1M Solution in Methylene Chloride
• Color: Yellow to Brown
• Molecular Formula: BBr3
• MDL Number: MFCD00011312
• Merck Index: 15, 1349
• InChI Key: ILAHWRKJUDSMFH-UHFFFAOYSA-N
• IUPAC Name: tribromoborane
• PubChem CID: 25134
• Concentration or Composition (by Analyte or Components): 0.9 to 1.1M
• Specific Gravity: 1.467

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage.
Fatal if inhaled.
Fatal if swallowed.
Suspected of causing cancer.
Reacts violently with water.
May cause drowsiness or dizziness.

GHS P Statement
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician.
Wear protective gloves/protective clothing/eye protection/face protection.

GHS Signal Word: Danger

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Recommended Storage : Darkens on storage

Product Identifier

• Boron tribromide, 1M solution in methylene chloride

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 2
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 A
• Specific target organ toxicity Category 3

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H330-Fatal if inhaled.
• H351-Suspected of causing cancer.
• H336-May cause drowsiness or dizziness.
• H300-Fatal if swallowed.
• EUH014-Reacts violently with water.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only