Boron tribromide, 1M soln. in dichloromethane, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11333716	Thermo Scientific Alfa Aesar L14880.AC	25 mL
11343716	Thermo Scientific Alfa Aesar L14880.AE	100 mL

Description

Boron tribromide is used as a reactant for luminescent polystyrene derivatives with sterically protected carbazolylborane moieties, high-quality boron-doped graphene via Wurtz-type reductive coupling reaction and micrometer-sized organic molecule-DNA hybrid structures. It is also used in bromination and cyclization reactions to prepare cyclopenta[1,3]cyclopropa[1,2-b]pyrrolizin-8-one. It acts as a liquid boron source used in p-type deposition processes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Boron tribromide is used as a reactant for luminescent polystyrene derivatives with sterically protected carbazolylborane moieties, high-quality boron-doped graphene via Wurtz-type reductive coupling reaction and micrometer-sized organic molecule-DNA hybrid structures. It is also used in bromination and cyclization reactions to prepare cyclopenta[1,3]cyclopropa[1,2-b]pyrrolizin-8-one. It acts as a liquid boron source used in p-type deposition processes.

Solubility
Miscible with ethanol and carbon tetrachloride.

Notes
Moisture sensitive. Reacts violently with water. Incompatible with alcohols, alkali metals, aluminum, sodium oxides and strong bases.

Chemical Identifiers

• CAS: 10294-33-4
• Molecular Weight (g/mol): 250.52
• InChI Key: ILAHWRKJUDSMFH-UHFFFAOYSA-N
• PubChem CID: 25134
• SMILES: BrB(Br)Br

• Molecular Formula: BBr3
• MDL Number: MFCD00011312
• Synonym: boron tribromide, borane, tribromo, boron bromide, tribromoboron, hsdb 327, tribromoboran, boron tribrornide, boron tri bromide, boron tri-bromide
• IUPAC Name: tribromoborane

Specifications

• CAS: 10294-33-4
• MDL Number: MFCD00011312
• Merck Index: 14,1347
• Solubility Information: Miscible with ethanol and carbon tetrachloride.
• SMILES: BrB(Br)Br
• Molecular Weight (g/mol): 250.52
• Formula Weight: 250.52
• Refractive Index: 1.434
• Density: 1.467

• Molecular Formula: BBr3
• UN Number: UN3390
• Synonym: boron tribromide, borane, tribromo, boron bromide, tribromoboron, hsdb 327, tribromoboran, boron tribrornide, boron tri bromide, boron tri-bromide
• InChI Key: ILAHWRKJUDSMFH-UHFFFAOYSA-N
• IUPAC Name: tribromoborane
• PubChem CID: 25134
• Concentration or Composition (by Analyte or Components): 1M soln. in dichloromethane
• Sensitivity: Moisture sensitive
• Chemical Name or Material: Boron tribromide

Safety and Handling

GHS H Statement
H300-H330-H314-H351
Fatal if swallowed.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Suspected of causing cancer.

P201-P202-P260-P264b-P270-P271-P281-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

H300+H330-H314-H335-H336-H350-H373

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Recommended Storage : Ambient temperatures; Store under Nitrogen

Product Identifier

• Boron tribromide, 1M solution in dichloromethane

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 2
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 A
• Specific target organ toxicity Category 3

Hazard Statement

• H300-Fatal if swallowed.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H330-Fatal if inhaled.
• H336-May cause drowsiness or dizziness.
• H351-Suspected of causing cancer.
• EUH014-Reacts violently with water.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : dichloromethane, boron tribromide

RUO – Research Use Only