Borane-methyl sulfide complex, 2M solution in THF, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10022420	Thermo Scientific Acros 185071000	100 mL	AcroSeal™ Glass bottle
10685252	Thermo Scientific Acros 185078000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Reduction reagent

Specifications

• Chemical Name or Material: Borane-methyl sulfide complex
• Name Note: 2M Solution in Tetrahydrofuran
• Molecular Formula: C2H9BS
• MDL Number: MFCD00013189
• Fieser: 04,191; 05,47; 06,64; 08,49; 10,49; 14,52; 17,50
• Merck Index: 15, 1336
• Solubility Information: Solubility in water: reacts. Other solubilities: soluble in ethyl ether, tetrahydrofurane, hexane,, toluene, methylene chloride and other aprotic, solvents
• SMILES: B.CSC
• Molecular Weight (g/mol): 75.96
• Formula Weight: 75.95
• Flash Point: −17°C

• Color: Colorless to Yellow
• CAS: 13292-87-0, 109-99-9, 75-18-3
• Linear Formula: (CH₃)₂S·BH₃
• Concentration: 1.80 to 2.20M
• Density: 0.8500g/mL
• Synonym: dimethyl sulfide borane, borane-methyl sulfide complex, borane dimethyl sulfide complex, borane-dimethyl sulfide, dimethyl sulfideborane, dimethyl sulfide trihydroboron, borane-dimethyl sulfide complex, borane methylsulfide, borane dimethylsulfide, borane dms
• InChI Key: RMHDLBZYPISZOI-UHFFFAOYSA-N
• IUPAC Name: (methylsulfanyl)methane borane
• PubChem CID: 9833925
• Specific Gravity: 0.85
• Physical Form: Solution

Safety and Handling

GHS H Statement
May cause respiratory irritation. Causes skin irritation. Causes serious eye damage. Harmful if swallowed. In contact with water releases flammable gases which may ignite spontaneously. Highly flammable liquid and vapor. May form explosive peroxides. Reacts violently with water. Suspected of causing cancer. May cause drowsiness or dizziness.

GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Danger

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missing translation for 'tsca' : TSCA

Product Identifier

• Borane-methyl sulfide complex, 2M solution in tetrahydrofuran

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H315-Causes skin irritation.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P332+P313-If skin irritation occurs: Get medical advice/attention.

RUO – Research Use Only