Acryloyl chloride, 96%, stab. with 400ppm phenothiazine, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11308395	Thermo Scientific Alfa Aesar L10363.09	10 g
11318395	Thermo Scientific Alfa Aesar L10363.18	50 g
11328395	Thermo Scientific Alfa Aesar L10363.30	250 g

Description

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Solubility
Miscible with water.

Notes
Moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with alcohols, oxidizing agents, strong bases and polymerizing initiators.

Chemical Identifiers

• CAS: 814-68-6
• Molecular Weight (g/mol): 90.51
• InChI Key: HFBMWMNUJJDEQZ-UHFFFAOYSA-N
• PubChem CID: 13140
• SMILES: ClC(=O)C=C

• Molecular Formula: C3H3ClO
• MDL Number: MFCD00000731
• Synonym: acryloyl chloride, acrylyl chloride, 2-propenoyl chloride, acrylic acid chloride, propenoyl chloride, acryloylchloride, chlorid kyseliny akrylove, unii-8k23o56tg5, chlorid kyseliny akrylove czech, acrylylchloride
• IUPAC Name: prop-2-enoyl chloride

Specifications

• CAS: 814-68-6
• Boiling Point: 74°C to 76°C
• Odor: Acrid
• Linear Formula: CH₂=CHCOCl
• MDL Number: MFCD00000731
• Beilstein: 635744
• Synonym: acryloyl chloride, acrylyl chloride, 2-propenoyl chloride, acrylic acid chloride, propenoyl chloride, acryloylchloride, chlorid kyseliny akrylove, unii-8k23o56tg5, chlorid kyseliny akrylove czech, acrylylchloride
• InChI Key: HFBMWMNUJJDEQZ-UHFFFAOYSA-N
• IUPAC Name: prop-2-enoyl chloride
• PubChem CID: 13140
• Percent Purity: 96%

• Density: 1.114
• Flash Point: −4°C (24°F)
• Molecular Formula: C3H3ClO
• Refractive Index: 1.435
• UN Number: 3383
• Sensitivity: Light and moisture sensitive
• Solubility Information: Miscible with water.
• SMILES: ClC(=O)C=C
• Molecular Weight (g/mol): 90.51
• Formula Weight: 90.51
• Chemical Name or Material: Acryloyl Chloride, stabilized with 400ppm phenothiazine

Safety and Handling

GHS H Statement
H225-H330-H314-H318-H302
Highly flammable liquid and vapor.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.

P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H225-H302-H314-H330-H335

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Recommended Storage : Keep cold; Store under Nitrogen

Product Identifier

• Acryloyl chloride

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 1
• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H302-Harmful if swallowed.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H330-Fatal if inhaled.
• EUH014-Reacts violently with water.
• EUH208-Contains . May produce an allergic reaction.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Acrylic acid chloride

RUO – Research Use Only