Acetylacetonato(norbornadiene)rhodium(I), Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10586173	Thermo Scientific Acros 382561000	100 mg	Glass bottle
10128712	Thermo Scientific Acros 382565000	500 mg	Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 32354-50-0
• Molecular Weight (g/mol): 294.16
• InChI Key: IIQPRGKBFZGPIB-LWFKIUJUSA-M
• SMILES: [Rh+].C\C([O-])=C\C(C)=O.C1C2C=CC1C=C2

• Molecular Formula: C12H15O2Rh
• MDL Number: MFCD00075071
• IUPAC Name: λ¹-rhodium(1+) bicyclo[2.2.1]hepta-2,5-diene (2Z)-4-oxopent-2-en-2-olate

Specifications

• Melting Point: 140.0°C
• Color: Yellow
• Molecular Formula: C12H15O2Rh
• Solubility Information: Solubility in water: insoluble.
• SMILES: [Rh+].C\C([O-])=C\C(C)=O.C1C2C=CC1C=C2
• Molecular Weight (g/mol): 294.16
• Infrared Spectrum: Authentic

• CAS: 32354-50-0
• Physical Form: Powder
• MDL Number: MFCD00075071
• InChI Key: IIQPRGKBFZGPIB-LWFKIUJUSA-M
• IUPAC Name: λ¹-rhodium(1+) bicyclo[2.2.1]hepta-2,5-diene (2Z)-4-oxopent-2-en-2-olate
• Formula Weight: 294.16
• Chemical Name or Material: Acetylacetonato(norbornadiene)rhodium(I)

Safety and Handling

GHS H Statement:
May cause respiratory irritation.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Harmful if inhaled.
Causes serious eye irritation.

GHS P Statement:
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of soap and water.
Avoid breathing dust/fume/gas/mist/vapors/spray.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.

GHS Signal Word: Warning

Product Identifier

• Acetylacetonato(norbornadiene)rhodium(I)

Signal Word

• Warning

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.
• H312-Harmful in contact with skin.
• H332-Harmful if inhaled.
• H302-Harmful if swallowed.

Precautionary Statement

• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P312-IF SWALLOWED: Call a POISON CENTER or doctor/physician/ if you feel unwell.
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

RUO – Research Use Only