4-Chlorophenylmagnesium bromide, 1M solution in diethyl ether, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10308762	Thermo Scientific Acros 377401000	100 mL	AcroSeal™ Glass Bottle in Tin Can
10540153	Thermo Scientific Acros 377408000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 873-77-8, 60-29-7
• Molecular Weight (g/mol): 215.76
• InChI Key: CDEMHJCJMMOFMB-UHFFFAOYSA-M
• PubChem CID: 101888
• SMILES: ClC1=CC=C([Mg]Br)C=C1

• Molecular Formula: C6H4BrClMg
• MDL Number: MFCD00009926
• Synonym: 4-chlorophenylmagnesium bromide, bromo p-chlorophenyl magnesium, bromo 4-chlorophenyl magnesium, p-chlorophenylmagnesium bromide, 4-chlorophenyl magnesium bromide, pubchem24069, 4-chlorophenylmagnesiumbromide, 4-chlorphenylmagnesium bromide, 4-chloro phenylmagnesiumbromide, 4-chlorophenyhnagnesium bromide, grignard reagent
• IUPAC Name: magnesium;chlorobenzene;bromide

Specifications

• Color: Black-Brown to Gray
• CAS Min %: 22.85, 69.54
• Molecular Formula: C6H4BrClMg
• MDL Number: MFCD00009926
• Density: 0.8500g/mL
• InChI Key: CDEMHJCJMMOFMB-UHFFFAOYSA-M
• IUPAC Name: magnesium;chlorobenzene;bromide
• PubChem CID: 101888
• Physical Form: Solution

• CAS: 873-77-8, 60-29-7
• CAS Max %: 30.46, 77.15
• Linear Formula: Cl(C₆H₄)MgBr
• Concentration: 0.9 to 1.2M
• Synonym: 4-chlorophenylmagnesium bromide, bromo p-chlorophenyl magnesium, bromo 4-chlorophenyl magnesium, p-chlorophenylmagnesium bromide, 4-chlorophenyl magnesium bromide, pubchem24069, 4-chlorophenylmagnesiumbromide, 4-chlorphenylmagnesium bromide, 4-chloro phenylmagnesiumbromide, 4-chlorophenyhnagnesium bromide, grignard reagent
• SMILES: ClC1=CC=C([Mg]Br)C=C1
• Molecular Weight (g/mol): 215.76
• Formula Weight: 215.76
• Chemical Name or Material: 4-Chlorophenylmagnesium bromide, 1M Solution in Diethyl Ether

Safety and Handling

GHS H Statement
Harmful if swallowed. May cause drowsiness or dizziness. Causes severe skin burns and eye damage. In contact with water releases flammable gases which may ignite spontaneously. Extremely flammable liquid and vapor. May form explosive peroxides. Reacts violently with water. Repeated exposure may cause skin dryness or cracking.

GHS P Statement
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Avoid breathing dust/fume/gas/mist/vapors/spray. Store in a dry place. Store in a closed container. Keep container tightly closed. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

Danger

Recommended Storage : Magnesium salts may crystallize below 20°C

Product Identifier

• 4-Chlorophenylmagnesium bromide, 1M solution in diethyl ether

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 1
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H224-Extremely flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.
• EUH066-Repeated exposure may cause skin dryness or cracking.

Precautionary Statement

• P233-Keep container tightly closed.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P312-IF SWALLOWED: Call a POISON CENTER or doctor/physician/ if you feel unwell.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P402+P404-Store in a dry place. Store in a closed container.

RUO – Research Use Only