3-Ethoxy-2-cyclohexen-1-one, 99%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11482327	Thermo Scientific Alfa Aesar A14224.09	10 g
11492327	Thermo Scientific Alfa Aesar A14224.18	50 g
11402337	Thermo Scientific Alfa Aesar A14224.30	250 g

Description

3-Ethoxy-2-cyclohexen-1-one is a useful intermediate for the preparation of 3-alkyl- or aryl-2-cyclohexen-1-ones, by addition of organometallic reagents and subsequent hydrolysis. It helps in kinetic enolate formation (LDA) and alkylation occurs at the 6-position, the Stork-Danheiser kinetic alkylation procedure, which has found extensive use in alicyclic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Ethoxy-2-cyclohexen-1-one is a useful intermediate for the preparation of 3-alkyl- or aryl-2-cyclohexen-1-ones, by addition of organometallic reagents and subsequent hydrolysis. It helps in kinetic enolate formation (LDA) and alkylation occurs at the 6-position, the Stork-Danheiser kinetic alkylation procedure, which has found extensive use in alicyclic synthesis.

Solubility
Slightly soluble in water.

Notes
Store at 4°C. Protect from heat. Store away from oxidizing agents.

Chemical Identifiers

• CAS: 5323-87-5
• Molecular Weight (g/mol): 140.18
• InChI Key: JWCFJPLIRVYENQ-UHFFFAOYSA-N
• PubChem CID: 79216
• SMILES: CCOC1=CC(=O)CCC1

• Molecular Formula: C8H12O2
• MDL Number: MFCD00001580
• Synonym: 3-ethoxy-2-cyclohexen-1-one, 3-ethoxycyclohex-2-enone, 2-cyclohexen-1-one, 3-ethoxy, 3-ethoxy-2-cyclohexenone, 3-ethoxy-2-cyclohexene-1-one, 3-ethoxycyclohex-2-ene-1-one, 1-ethoxycyclohexene-3-one, acmc-209l4y, 3-ethoxy-2-cyclohexen-one, 3-ethoxy-cyclohex-2-enone
• IUPAC Name: 3-ethoxycyclohex-2-en-1-one

Specifications

• CAS: 5323-87-5
• Boiling Point: 76°C to 78°C (1 mmHg)
• Molecular Formula: C8H12O2
• MDL Number: MFCD00001580
• Synonym: 3-ethoxy-2-cyclohexen-1-one, 3-ethoxycyclohex-2-enone, 2-cyclohexen-1-one, 3-ethoxy, 3-ethoxy-2-cyclohexenone, 3-ethoxy-2-cyclohexene-1-one, 3-ethoxycyclohex-2-ene-1-one, 1-ethoxycyclohexene-3-one, acmc-209l4y, 3-ethoxy-2-cyclohexen-one, 3-ethoxy-cyclohex-2-enone
• InChI Key: JWCFJPLIRVYENQ-UHFFFAOYSA-N
• IUPAC Name: 3-ethoxycyclohex-2-en-1-one
• PubChem CID: 79216
• Percent Purity: 99%

• Density: 1.04
• Flash Point: 107°C (224°F)
• Refractive Index: 1.506
• Beilstein: 2042049
• Solubility Information: Slightly soluble in water.
• SMILES: CCOC1=CC(=O)CCC1
• Molecular Weight (g/mol): 140.18
• Formula Weight: 140.18
• Chemical Name or Material: 3-Ethoxy-2-cyclohexen-1-one

Safety and Handling

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missing translation for 'tsca' : No

Recommended Storage : Store at -20°C

RUO – Research Use Only