Phosphorus oxychloride, 99%, Thermo Scientific Chemicals

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

C-X bond formation reagent, Oxidation reagent

Chemical Identifiers

• CAS: 10025-87-3
• InChI Key: XHXFXVLFKHQFAL-UHFFFAOYSA-N
• PubChem CID: 24813
• SMILES: O=P(Cl)(Cl)Cl

• MDL Number: MFCD00011443
• Synonym: phosphorus oxychloride, phosphoryl chloride, phosphoric trichloride, phosphoryl trichloride, phosphoroxychloride, trichlorophosphine oxide, phosphorus oxytrichloride, fosforoxychlorid, phosphorous oxychloride, phosphorylchlorid
• ChEBI: CHEBI:30336

Specifications

• CAS: 10025-87-3
• Assay Percent Range: 99%
• Linear Formula: POCl₃
• Fieser: 01,876; 02,330; 03,228; 04,390; 05,535; 07,292; 09,374; 11,429; 13,249; 15,267; 17,288
• Synonym: phosphorus oxychloride, phosphoryl chloride, phosphoric trichloride, phosphoryl trichloride, phosphoroxychloride, trichlorophosphine oxide, phosphorus oxytrichloride, fosforoxychlorid, phosphorous oxychloride, phosphorylchlorid
• SMILES: O=P(Cl)(Cl)Cl
• PubChem CID: 24813
• Formula Weight: 153.33
• Refractive Index: 1.4600 to 1.4620 (20°C, 589nm)
• Chemical Name or Material: Phosphorus oxychloride

• Physical Form: Liquid
• Molecular Formula: Cl3OP
• MDL Number: MFCD00011443
• Merck Index: 15, 7461
• InChI Key: XHXFXVLFKHQFAL-UHFFFAOYSA-N
• Molecular Weight (g/mol): 153.323
• ChEBI: CHEBI:30336
• Percent Purity: ≥98.5% (ex Cl)
• Density: 1.6450g/mL

Safety and Handling

GHS H Statement:
Fatal if inhaled.
Causes damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
Harmful if swallowed.
Contact with water liberates toxic gas.
Reacts violently with water.

GHS P Statement:
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
Wear eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Do not breathe dust/fume/gas/mist/vapors/spray.

WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.

Danger

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missing translation for 'rtecsNumber' : TH4897000

missing translation for 'tsca' : TSCA

Product Identifier

• Phosphorus oxychloride

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 2
• Skin corrosion/irritation Category 1 A
• Serious eye damage/eye irritation Category 1
• Specific target organ toxicity Category 1
• Substances and mixtures corrosive to metals Category 1
• Acute toxicity Category 4

Hazard Statement

• H302-Harmful if swallowed.
• H330-Fatal if inhaled.
• H314-Causes severe skin burns and eye damage.
• H372-Causes damage to organs.
• H290-May be corrosive to metals.
• EUH029-Contact with water liberates toxic gas.
• EUH014-Reacts violently with water.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P260-Do not breathe dust/fume/gas/mist/vapours/spray.
• P310-Immediately call a POISON CENTER/doctor/.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.

RUO – Research Use Only