Bismuth(III) nitrate pentahydrate, 98%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11419293	Thermo Scientific Alfa Aesar A11748.22	100 g
11429293	Thermo Scientific Alfa Aesar A11748.36	500 g

Description

Bismuth(III) nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Bismuth(III) nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.

Solubility
Soluble in dilute nitric acid solution, dilute acetic acid, glycerol and acetone. Insoluble in alcohol, ethyl acetateSoluble in acetone, acetic acid and glycerol. Insoluble in ethanol and ethyl acetate.

Notes
Hygroscopic. Moisture sensitive. Incompatible with strong acids, strong reducing agents, strong oxidizing agents, powdered metals and organic materials.

Chemical Identifiers

• CAS: 10035-06-0
• Molecular Weight (g/mol): 485.07
• InChI Key: FBXVOTBTGXARNA-UHFFFAOYSA-N
• PubChem CID: 160911
• SMILES: O.O.O.O.O.[Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

• Molecular Formula: BiH10N3O14
• MDL Number: MFCD00149157
• Synonym: bismuth nitrate pentahydrate, bismuth trinitrate pentahydrate, bismuth nitrate, hydrate 1:5, bismuth iii nitrate pentahydrate, unii-fo2icy167b, fo2icy167b, nitric acid, bismuth 3+ salt, pentahydrate, acmc-20alle, bismuthnitratepentahydrate
• IUPAC Name: bismuth;trinitrate;pentahydrate

Specifications

• Melting Point: 30°C (decomposition)
• Molecular Formula: BiH10N3O14
• UN Number: UN1477
• Synonym: bismuth nitrate pentahydrate, bismuth trinitrate pentahydrate, bismuth nitrate, hydrate 1:5, bismuth iii nitrate pentahydrate, unii-fo2icy167b, fo2icy167b, nitric acid, bismuth 3+ salt, pentahydrate, acmc-20alle, bismuthnitratepentahydrate
• InChI Key: FBXVOTBTGXARNA-UHFFFAOYSA-N
• IUPAC Name: bismuth;trinitrate;pentahydrate
• PubChem CID: 160911
• Percent Purity: 98%
• Sensitivity: Hygroscopic
• Chemical Name or Material: Bismuth (III) nitrate pentahydrate

• CAS: 10035-06-0
• MDL Number: MFCD00149157
• Merck Index: 14,1271
• Solubility Information: Soluble in dilute nitric acid solution,dilute acetic acid,glycerol and acetone. Insoluble in alcohol,ethyl acetateSoluble in acetone,acetic acid and glycerol. Insoluble in ethanol and ethyl acetate.
• SMILES: O.O.O.O.O.[Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
• Molecular Weight (g/mol): 485.07
• Formula Weight: 485.07 (394.99 Anhydrous)
• Odor: Odorless
• Density: 2.83

Safety and Handling

GHS H Statement
H272-H315-H319-H335
May intensify fire
oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P201-P202-P210-P220-P221-P261-P262-P264b-P271-P280i-P281-P302+P352-P304+P340-P305+P351+P338-P308+P313-P332+P313-P362-P370+P378q-P501c

H272-H315-H319-H335-H373

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missing translation for 'einecsNumber' : 233-791-8

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

Product Identifier

• Bismuth(III) nitrate pentahydrate

Signal Word

• Danger

Hazard Category

• Oxidising solid Category 2
• Skin corrosion/irritation Category 2
• Serious eye damage/eye irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H272-May intensify fire; oxidiser.
• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P220-Keep/Store away from clothing/combustible materials.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P337+P313-If eye irritation persists: Get medical advice/attention.
• P405-Store locked up.
• P501-Dispose of contents/container to .

RUO – Research Use Only