4-Fluorophenylmagnesium bromide, 0.8M solution in THF, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10240703	Thermo Scientific Acros 377231000	100 mL	AcroSeal™ Glass bottle
10588093	Thermo Scientific Acros 377238000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 352-13-6, 109-99-9
• Molecular Weight (g/mol): 199.31
• InChI Key: QYBFFRXNNFXREA-UHFFFAOYSA-M
• PubChem CID: 2734897
• SMILES: FC1=CC=C([Mg]Br)C=C1

• Molecular Formula: C6H4BrFMg
• MDL Number: MFCD00009667
• Synonym: 4-fluorophenylmagnesium bromide, magnesium, bromo 4-fluorophenyl, bromo 4-fluorophenyl magnesium, p-fluorophenylmagnesium bromide, 4-fluorophenyl magnesium bromide, 4-f-c6h4-mgbr, 4-fluorophenylmagnesiumbromide, 4-fluorphenylmagnesium bromide, 4-flourophenylmagnesium bromide, 4-fluorophenyl magnesiumbromide, grignard reagent
• IUPAC Name: bromo(4-fluorophenyl)magnesium

Specifications

• Color: Yellow to Brown
• Melting Point: 5.0°C
• Linear Formula: F(C₆H₆)MgBr
• Density: 1.0100g/mL
• Solubility Information: Solubility in water: vigorous reaction.
• SMILES: FC1=CC=C([Mg]Br)C=C1
• Molecular Weight (g/mol): 199.31
• Formula Weight: 199.3
• Specific Gravity: 1.01
• Physical Form: Solution

• CAS: 352-13-6, 109-99-9
• Molecular Formula: C6H4BrFMg
• MDL Number: MFCD00009667
• Synonym: 4-fluorophenylmagnesium bromide, magnesium, bromo 4-fluorophenyl, bromo 4-fluorophenyl magnesium, p-fluorophenylmagnesium bromide, 4-fluorophenyl magnesium bromide, 4-f-c6h4-mgbr, 4-fluorophenylmagnesiumbromide, 4-fluorphenylmagnesium bromide, 4-flourophenylmagnesium bromide, 4-fluorophenyl magnesiumbromide, grignard reagent
• InChI Key: QYBFFRXNNFXREA-UHFFFAOYSA-M
• IUPAC Name: bromo(4-fluorophenyl)magnesium
• PubChem CID: 2734897
• Percent Purity: 14 to 17%
• Flash Point: −21°C
• Chemical Name or Material: 4-Fluorophenylmagnesium bromide, 0.8M Solution in THF

Safety and Handling

GHS P Statement May cause respiratory irritation. Causes severe skin burns and eye damage. Suspected of causing cancer. Highly flammable liquid and vapor. In contact with water releases flammable gas. Reacts violently with water. May form explosive peroxides.

GHS P Statement Avoid breathing dust/fume/gas/mist/vapors/spray. Keep container tightly closed. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Danger

Recommended Storage : product may develop some turbidity or precipitate during storage

Product Identifier

• 4-Fluorophenylmagnesium bromide, 0.8M solution in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 2

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H261-In contact with water releases flammable gases.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

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RUO – Research Use Only