1,6-Diaminohexane, 98+%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11469080	Thermo Scientific Alfa Aesar A14212.22	100 g
11479080	Thermo Scientific Alfa Aesar A14212.36	500 g
11459080	Thermo Scientific Alfa Aesar A14212.0E	2500 g
17426742	Thermo Scientific Alfa Aesar A14212-A3	2 kg

Description

1,6-Diaminohexane is mainly used as a monomer to make nylon 6-6. Its derivative hexamethylene diisocyanate (HDI) is used in the production of polyurethane. It acts as a cross-linking agent in epoxy resins. Other applications include coatings, lubricants and water treatment products.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,6-Diaminohexane is mainly used as a monomer to make nylon 6-6. Its derivative hexamethylene diisocyanate (HDI) is used in the production of polyurethane. It acts as a cross-linking agent in epoxy resins. Other applications include coatings, lubricants and water treatment products.

Solubility
Soluble in water. Slightly soluble in ether, alcohol and benzene.

Notes
Air sensitive and hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids, strong oxidizing agents, acid chlorides, carbon dioxide and acid anhydrides.

Chemical Identifiers

• CAS: 124-09-4
• MDL Number: MFCD00008243
• Synonym: 1,6-hexanediamine, 1,6-diaminohexane, hexamethylenediamine, hmda, 1,6-hexylenediamine, 1,6-hexamethylenediamine, 1,6-diamino-n-hexane, hexamethylene diamine, hexylenediamine, 1,6-hexanediamine solution
• ChEBI: CHEBI:39618

• Molecular Formula: C6H16N2
• InChI Key: NAQMVNRVTILPCV-UHFFFAOYSA-N
• PubChem CID: 16402
• IUPAC Name: hexane-1,6-diamine

Specifications

• CAS: 124-09-4
• Density: 0.84
• Boiling Point: 199°C to 204°C
• Odor: Amine-like
• Linear Formula: H₂N(CH₂)₆NH₂
• UN Number: UN2280
• Sensitivity: Air sensitive; Hygroscopic
• Synonym: 1,6-hexanediamine, 1,6-diaminohexane, hexamethylenediamine, hmda, 1,6-hexylenediamine, 1,6-hexamethylenediamine, 1,6-diamino-n-hexane, hexamethylene diamine, hexylenediamine, 1,6-hexanediamine solution
• InChI Key: NAQMVNRVTILPCV-UHFFFAOYSA-N
• IUPAC Name: hexane-1,6-diamine
• PubChem CID: 16402
• Formula Weight: 116.21
• Chemical Name or Material: 1,6-Diaminohexane

• Melting Point: 39°C to 43°C
• pH: 12.4
• Flash Point: 85°C (185°F)
• Molecular Formula: C6H16N2
• MDL Number: MFCD00008243
• Beilstein: 1098307
• Merck Index: 14,4695
• Solubility Information: Soluble in water. Slightly soluble in ether,alcohol and benzene.
• SMILES: C(CCCN)CCN
• Molecular Weight (g/mol): 116.208
• ChEBI: CHEBI:39618
• Percent Purity: ≥98%

Safety and Handling

GHS H Statement
H314-H318-H302-H312-H335
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
Harmful in contact with skin.
May cause respiratory irritation.

P210-P235-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H227-H302+H312-H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: HEXAMETHYLENEDIAMINE, SOLID

missing translation for 'einecsNumber' : 204-679-6

missing translation for 'rtecsNumber' : MO1180000

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

Product Identifier

• 1,6-Diaminohexane

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3

Hazard Statement

• H302-Harmful if swallowed.
• H312-Harmful in contact with skin.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H335-May cause respiratory irritation.

Precautionary Statement

• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P302+P352-IF ON SKIN: Wash with plenty of water/soap.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : 1,6-Hexanediamine

RUO – Research Use Only